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(1alpha,3beta,4beta,6alpha)-3,7,7-trimethylbicyclo[4.1.0]heptane-3,4-diol

  • Chemical Name: (1alpha,3beta,4beta,6alpha)-3,7,7-trimethylbicyclo[4.1.0]heptane-3,4-diol
  • CAS: 19898-60-3
  • Purity: 99%
Inquiry

(1alpha,3beta,4beta,6alpha)-3,7,7-trimethylbicyclo[4.1.0]heptane-3,4-diol GMP Manufacturer Global Trade 19898-60-3 with Fast Delivery

  • Molecular Formula: C10H18O2
  • Molecular Weight: 170.252
  • Boiling Point: 272.8°Cat760mmHg 
  • Flash Point: 126.6°C 
  • Density: 1.091g/cm3 

19898-60-3 Relevant articles

Monoterpenediol insect repellents

-

, (2008/06/13)

An insect repellent comprising as an act...

ONE-POT TWO-STEP SYNTHESIS OF 1,2-DIOL

Fringuelli, F.,Germani, R.,Pizzo, F.,Savelli, G.

, p. 1939 - 1944 (2007/10/02)

Diols can be prepared by hydroxilation o...

Transformations of 3-carene oxide at rhenium-containing catalysts

Manukov, E. N.,Bazhina, G. N.

, p. 106 - 110 (2007/10/02)

The transformations of 3-carene oxide at...

STEREOCHEMISTRY OF THE CARANE SYSTEM. OXIDATION PRODUCTS OF ISOMERIC 3,4-CARANEDIOLS OBTAINED FROM (+)-3-CARENE

Hendrich, Aleksandra,Piatkowski, Krzysztof

, p. 73 - 84 (2007/10/02)

Oxidation of four isomeric 3,4-caranedio...

19898-60-3 Process route

α-3,4-Epoxycarane
936-91-4,936-92-5,2225-98-1,21218-11-1,35671-18-2

α-3,4-Epoxycarane

3,6,6-trimethylbicyclo<3.1.0>hexane-3-carboxaldehyde
13124-67-9

3,6,6-trimethylbicyclo <3.1.0> hexane-3-carboxaldehyde

cis-carane-4-one
4176-01-6,4176-04-9,13124-69-1,24278-58-8,43124-59-0,43124-60-3,52153-58-9,135559-92-1

cis-carane-4-one

3β,4α-dihydroxy-3-carane
10395-46-7,19898-58-9,19898-59-0,19898-60-3,19898-61-4,22556-08-7,38741-11-6,57457-02-0,57526-47-3,81371-67-7

3β,4α-dihydroxy-3-carane

trans-4-caranone
4176-01-6,4176-04-9,13124-69-1,24278-58-8,43124-59-0,43124-60-3,52153-58-9,135559-92-1

trans-4-caranone

Conditions
Conditions Yield
rhenium(VII) oxide on aluminum oxide; at 150 ℃; for 0.0833333h; Further byproducts given; in a sealed tube;
15.0 % Chromat.
8.6 % Chromat.
8.1 % Chromat.
25.2 % Chromat.
3β-hydroxycarane-4-one

3β-hydroxycarane-4-one

1S,3R,4S,6R-(+)-3β,4β-caranediol
10395-46-7,19898-58-9,19898-59-0,19898-60-3,19898-61-4,22556-08-7,38741-11-6,57457-02-0,57526-47-3,81371-67-7

1S,3R,4S,6R-(+)-3β,4β-caranediol

Conditions
Conditions Yield
With sodium hydroxide; In hexane; water; ethyl acetate;

19898-60-3 Upstream products

  • 498-15-7
    498-15-7

    (+)-Δ3 -carene

  • 936-92-5
    936-92-5

    (1S,3R,4S,6R)-3,4-epoxy-3,7,7-trimethylbicyclo[4.1.0]heptane

  • 13466-78-9
    13466-78-9

    3-carene

  • 936-91-4
    936-91-4

    (1S,3R,4S,6R)-3,4-epoxycarane

19898-60-3 Downstream products

  • 22556-08-7
    22556-08-7

    trans-3,4-caranediol

  • 33116-78-8
    33116-78-8

    (1S,3R)-(+)-3-hydroxy-4-isocaranyl tosylate

  • 10395-46-7
    10395-46-7

    (+)-3α,4β-caranediol

  • 36482-69-6
    36482-69-6

    (1R,4S,6S)-4-hydroxy-4,7,7-trimethylbicyclo[4.1.0]heptan-3-one

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